Enhancement Mechanical Properties of Simalambuo Wood (Loppophetalum spp) Delignified using NaOH in The Thermomechanical Densification Method

Authors

  • Nur Azizah Universitas Sumatera Utara
  • Febri Sindika Universitas Sumatera Utara
  • Andriayani Andriayani Universitas Sumatera Utara
  • Saharman Gea Universitas Sumatera Utara

Keywords:

Delignification, densified, modulus of rupture (moe), modulus of elasticity (mor), surface hardness

Abstract

One of the problems with fast-growing wood is the low density, which causes poor mechanical properties, so a densification process is carried out to increase the wood's density, surface hardness, and strength. In this study, the delignification process using NaOH was carried out at variations of 12.24, and 48 hours and then continued with the thermomechanical densification process. This study decreased lignin content in delignification simalambuo wood from 30% to 4%. The value of the Modulus of Rupture, Modulus of elasticity, and surface hardness increases with increasing immersion time during the delignification process. The highest values of Modulus of Rupture, Modulus of elasticity, and surface hardness were obtained by simalambuo wood soaked for 48 hours, namely, 2828.23 kg/cm2, 97.47 kg/cm2, and 256.73 kg/cm2.

Author Biographies

Nur Azizah, Universitas Sumatera Utara

1Postgraduate Program of Chemistry, Faculty of Mathematics and Natural Science

Febri Sindika, Universitas Sumatera Utara

2Department of Chemistry, Faculty of Mathematics and Natural Science 

Andriayani Andriayani, Universitas Sumatera Utara

1Postgraduate Program of Chemistry, Faculty of Mathematics and Natural Science

2Department of Chemistry, Faculty of Mathematics and Natural Science

Saharman Gea, Universitas Sumatera Utara

1Postgraduate Program of Chemistry, Faculty of Mathematics and Natural Science 

2Department of Chemistry, Faculty of Mathematics and Natural Science 

3Cellulosic and Functional Materials Research Centre 

References

Budakçi, M., Pelit, H., Sönmez, A., & Korkmaz, M. (2016). The effects of densification and heat post-treatment on hardness and morphological properties of wood materials. BioResources, 11(3), 7822–7838.

Esteves, B., Ribeiro, F., Cruz-lopes, L., Ferreira, J., Domingos, I., Duarte, M., Duarte, S., & Nunes, L. (2017). Densification and heat treatment of maritime pine wood. Wood Research, 62(3), 373-388.

Frey, M., Widner, D., Segmehl, J. S., Casdorff, K., Keplinger, T., & Burgert, I. (2018). Delignified and densified cellulose bulk materials with excellent tensile properties for sustainable engineering. ACS Applied Materials and Interfaces, 10(5), 5030–5037.

Gong, M., Lamason, C., & Li, L. (2010). Interactive effect of surface densification and post-heat-treatment on aspen wood. Journal of Materials Processing Technology, 210(2), 293–296.

He, Z., Qu, L., Wang, Z., Qian, J., & Yi, S. (2019). Effects of zinc chloride–silicone oil treatment on wood dimensional stability, chemical components, thermal decomposition and its mechanism. Scientific Reports, 9(Februaary), 1–7.

Jiang, J., Zhou, Y., Mei, C., & Cao, J. (2021). Polyethylene glycol and silica sol penetration improves hydrophobicity and dimensional stability of wood after a short-time treatment. European Journal of Wood and Wood Products, 79(6), 1395–1404.

Juliaty, N., & Ernayati. (2003). Perupuk (Lophopetalum javanicum) salah satu jenis andalan Kalimantan Timur. Bogor: Komatsu-JICA.

Kiaei, M., Rad, M. B., & Amani, N. (2018). Influence of densification temperature on some physical and mechanical properties of pterocarya fraxinifolia wood. Drvna Industrija, 69(3), 283–287.

Laine, K., Segerholm, K., Wålinder, M., Rautkari, L., & Hughes, M. (2016). Wood densification and thermal modification: Hardness, set-recovery and micromorphology. Wood Science and Technology, 50(5), 883–894.

Li, P., Zhang, Y., Zuo, Y., Lu, J., Yuan, G., & Wu, Y. (2020). Preparation and characterization of sodium silicate impregnated Chinese fir wood with high strength, water resistance, flame retardant and smoke suppression. Journal of Materials Research and Technology, 9(1), 1043–1053.

Mania, P., Wróblewski, M., Wójciak, A., Roszyk, E., & Moliński, W. (2020). Hardness of densified wood in relation to changed chemical composition. Forests, 11(5), 1–12.

Okon, K. E., Lin, F., Lin, X., Chen, C., Chen, Y., & Huang, B. (2018). Modification of Chinese fir (cunninghamia lanceolata l.) wood by silicone oil heat treatment with micro-wave pretreatment. European Journal of Wood and Wood Products, 76(1), 221–228.

Raman, V., & Liew, K. C. (2020). Density of densified paraserianthes falcataria wood pre-treated with alkali. IOP Conference Series: Earth and Environmental Science (pp. 1-5). United Kingdom: IOP Publishing Ltd.

Reinprecht, L. (2016). Modifying Protection of Wood. Modifying Protection of Wood Methodology, ecology and effectiveness of wood (pp. 218-259). United States: John Wiley & Sons, Ltd.

Shi, J., Peng, J., Huang, Q., Cai, L., & Shi, S. Q. (2020). Fabrication of densified wood via synergy of chemical pretreatment, hot-pressing and post mechanical fixation. Journal of Wood Science, 66(5), 1-9.

Yu, Y., Zhang, F., Zhu, S., & Li, H. (2017). Effects of high-pressure treatment on poplar wood: density profile, mechanical properties, strength potential index, and microstructure. BioResources, 12(3), 6283–6297.

Yunianti, A. D., Tirtayasa, P. K., Suhasman., Taskirawati, I., Agussalim., & Muin, M. (2019). Modified densification process for increasing strength properties of pine and gmelina wood from community forests. Journal of the Korean Wood Science and Technology, 47(4), 418–424.

Zhang, N., Xu, M., & Cai, L. (2019). Improvement of mechanical, humidity resistance and thermal properties of heat-treated rubber wood by impregnation of SiO2 precursor. Scientific Reports, 9(January), 1–9.

Downloads

Published

2022-11-30

How to Cite

Azizah, N. ., Sindika, F. ., Andriayani, A., & Gea, S. . (2022). Enhancement Mechanical Properties of Simalambuo Wood (Loppophetalum spp) Delignified using NaOH in The Thermomechanical Densification Method. Jurnal Akademika Kimia, 11(4), 231–235. Retrieved from https://jurnal.fkip.untad.ac.id/index.php/jak/article/view/2599

Issue

Section

Articles

Most read articles by the same author(s)