Development of Nanocomposite Films with Durian Peel Nanocrystalline Cellulose

Authors

  • Zeinur Rochma Fandis Romadhon Universitas Negeri Surabaya
  • I Gusti Made Sanjaya

DOI:

https://doi.org/10.22487/j24775185.2021.v10.i4.pp230-236

Keywords:

NCC, nanocomposite film, durian peel

Abstract

This research aims to synthesize and characterize nanocomposite film with nanocrystalline cellulose (NCC) durian peel waste filler. Nanocomposite film was prepared by adding NCC with concentrations of 0%, 1%, 3%, 5%, and 7% to each mixture of chitosan and guar gum. Characterization of nanocomposite film includes tensile strength test, elongation test, water-resistance test, and biodegradability. Nanocomposite film with NCC 7% showed a tensile strength value of 21.988 MPa; elongation of 10.3%; and experienced degradability of 4.05 mg/day, besides the characterization of the equal distribution of NCC in the chitosan-guar gum matrix was proven from the SEM results.

References

Khalil, H. P. S. A., Davoudpour, Y., Aprilia, N. A. S., Mustapha, A., Islam, Md. N., & Dungani, R. (2014). Nanocellulose-based polymer nanocomposite: Isolation, characterization, and applications. In V. K. Thakur (Ed.), Nanocellulose Polymer Nanocomposites: Fundamentals and Applications (pp. 273–309). Washington: Wiley Blackwell.

Afif, M., Wijayati, N., & Mursiti, S. (2018). Pembuatan dan karakterisasi bioplastik dari pati biji alpukat-kitosan dengan plasticizer sorbitol. Indonesian Journal of Chemical Science, 7(2), 102–109.

Anggarini, F. (2013). Aplikasi plasticizer gliserol pada pembuatan plastik biodegradable dari biji nangka. Unpublished Undergraduate Thesis. Semarang: Universitas Negeri Semarang.

Arini, D., Ulum, M. S., & Kasman. (2017). Pembuatan dan pengujian sifat mekanik plastik biodegradable berbasis tepung biji durian. Natural Science: Journal of Science and Technology, 6(3), 276–283.

Celebi, H., & Kurt, A. (2015). Effects of processing on the properties of chitosan/cellulose nanocrystal films. Carbohydrate Polymers, 133(November), 284–293.

Abugoch, L. E., Tapia, C., Villamán, M. C., Yazdani-Pedram, M., & Díaz-Dosque, M. (2011). Characterization of quinoa protein–chitosan blend edible films. Food Hydrocolloids, 25(5), 879–886.

Effendi, D. B., Rosyid, N. H., Nandiyanto, A. B. D., & Mudzakir, A. (2015). Review : Sintesis Nanoselulosa. Jurnal Integrasi Proses, 5(2), 61–74.

George, J., Ramana, K. V., Bawa, A. S., & Siddaramaiah. (2011). Bacterial cellulose nanocrystals exhibiting high thermal stability and their polymer nanocomposites. International Journal of Biological Macromolecules, 48(1), 50–57.

Ginting, M. H. S., Kristiani, M., Amelia, Y., & Hasibuan, R. (2016). The effect of chitosan , sorbitol, and heating temperature bioplastic solution on mechanical properties of bioplastic from durian seed starch (durio zibehinus). International Journal of Engineering Research and Applications, 6(1), 33–38.

Govin, A., Schmidt, W., Bartholin, M.-C., & Grosseau, P. (2017). Combination of guar gum derivatives and superplasticizers, impact on properties of Portland cement-pastes. Concrete 2017 - Advances in Concrete Materials and Structures and 3rd International Congress on Durability of Concrete (pp. 1–10). Adélaïde, Australia.

Haafiz, M. K. M., Hassan, A., Zakaria, Z., & Inuwa, I. M. (2014). Isolation and characterization of cellulose nanowhiskers from oil palm biomass microcrystalline cellulose. Carbohydrate Polymers, 103(March), 119–125.

Hamid, S. B. A., Chowdhury, Z. Z., Karim, Md. Z., & Ali, Md. E. (2016). Catalytic isolation and physicochemical properties of nanocrystalline cellulose (NCC) using HCl-FeCl3 system combined with ultrasonication. BioResources, 11(2), 3840–3855.

Hartati, N., Kemala, T., Sutriah, K., & Farobie, O. (2019). Kompatibilitas nanokristal selulosa termodifikasi setrimonium klorida (CTAC) dalam matriks poliasam laktat sebagai material pengemas. Jurnal Kimia Sains dan Aplikasi, 22(4), 157–163.

Illing, I., & MB, S. (2017). Uji ketahanan air bioplastik dari limbah ampas sagu dengan penambahan variasi konsentrasi gelatin. Prosiding Seminar Nasional Universitas Cokroaminoto Palopo (pp. 182–189). Palopo: Universitas Cokroaminoto Palopo.

Khan, A., Khan, R. A., Salmieri, S., Tien, C. L., Riedl, B., Bouchard, J., Chauve, G., Tan, V., Kamal, M. R., & Lacroix, M. (2012). Mechanical and barrier properties of nanocrystalline cellulose reinforced chitosan based nanocomposite films. Carbohydrate Polymers, 90(4), 1601–1608.

Khan, R. A., Salmieri, S., Dussault, D., Uribe-Calderon, J., Kamal, M. R., Safrany, A., & Lacroix, M. (2010). Production and properties of nanocellulose-reinforced methylcellulose-based biodegradable films. Journal of Agricultural and Food Chemistry, 58(13), 7878–7885.

Lubambo, A. F., de Freitas, R. A., Sierakowski, M-R., Lucyszyn, N., Sassaki, G. L., Serafim, B. M., & Saul, C. K. (2013). Electrospinning of commercial guar-gum: Effects of purification and filtration. Carbohydrate Polymers, 93(2), 484–491.

de Mesquita, J. P., Donnici, C. L., & Pereira, F. V. (2010). Biobased nanocomposites from layer-by-layer assembly of cellulose nanowhiskers with chitosan. Biomacromolecules, 11(2), 473–480.

Natalia, E. V., & Muryeti. (2020). Pembuatan plastik biodegradable dari pati singkong dan kitosan. Journal Printing and Packaging Technology, 1(1), 57–68.

Nuraeni, W., Daruwati, I., Maria, E., & Sriyani, M. E. (2013). Verifikasi kinerja alat particle size analyzer (PSA) horiba Lb-550 untuk penentuan distribusi ukuran nanopartikel. Prosiding Seminar Nasional Sains Dan Teknologi Nuklir (pp. 266–271). Bandung: Pusat Teknologi Nuklir Bahan dan Radiometri-BATAN.

Nurrohmah, K., Sari, A. K., Riziani, D., & Kusumasari, S. (2021). MAKUDU (Makaroni kulit durian): Potensi pangan olahan praktis untuk mengurangi limbah kulit durian. Jurnal Ilmiah Teknologi dan Industri Pangan UNISRI, 6(1), 30–40.

Putri, E., & Gea, S. (2018). Isolasi dan karakterisasi nanokistral selulosa dari tandan sawit (elaeis guineensis jack). Elkawnie: Journal of Islamic Science and Technology, 4(1), 13–22.

Rao, M. S., Kanatt, S. R., Chawla, S. P., & Sharma, A. (2010). Chitosan and guar gum composite films: Preparation, physical, mechanical and antimicrobial properties. Carbohydrate Polymers, 82(4), 1243–1247.

Siqueira, G., Bras, J., & Dufresne, A. (2010). New process of chemical grafting of cellulose nanoparticles with a long chain isocyanate. Langmuir, 26(1), 402–411.

Sujatno, A., Salam, R., Bandriyana., & Dimyati, A. (2017). Studi scanning electron microscopy (SEM) untuk karakterisasi proses oxidasi paduan zirkonium. Jurnal Forum Nuklir, 9(1), 44–50.

Tang, Y., Zhang, X., Zhao, R., Guo, D., & Zhang, J. (2018). Preparation and properties of chitosan/guar gum/nanocrystalline cellulose nanocomposite films. Carbohydrate Polymers, 197(October), 128–136.

Ureña-Benavides, E. E., Brown, P. J., & Kitchens, C. L. (2010). Effect of jet stretch and particle load on cellulose nanocrystal−alginate nanocomposite fibers. Langmuir, 26(17), 14263–14270.

Wei, L., Agarwal, U. P., Hirth, K. C., Matuana, L. M., Sabo, R. C., & Stark, N. M. (2017). Chemical modification of nanocellulose with canola oil fatty acid methyl ester. Carbohydrate Polymers, 169(August), 108–116.

Yuniastuti, E., Anggita, A., Nandariyah, & Sukaya. (2018). Local durian (Durio zibethinus murr.) exploration for potentially superior tree as parents in Ngrambe District, Ngawi. IOP Conference Series: Earth and Environmental Science (pp. 1–9). Orlando: IOP Publishing.

Zhao, G., Lyu, X., Lee, J., Cui, X., & Chen, W. (2019). Biodegradable and transparent cellulose film prepared eco-friendly from durian rind for packaging application. Food Packaging and Shelf Life, 21(September), 1–6.

Zhokh, A., & Strizhak, P. (2018). Thiele modulus having regard to the anomalous diffusion in a catalyst pellet. Chaos, Solitons and Fractals, 109(April), 58–63.

Zik, N. A. F. A., Sulaiman, S., & Jamal, P. (2020). Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bed reactor. Renewable Energy, 155(August), 267–277.

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Published

2021-11-30

How to Cite

Romadhon, Z. R. F., & Made Sanjaya, I. G. . (2021). Development of Nanocomposite Films with Durian Peel Nanocrystalline Cellulose. Jurnal Akademika Kimia, 10(4), 230–236. https://doi.org/10.22487/j24775185.2021.v10.i4.pp230-236

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